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61.
The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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Subglacial and subaqueous sediments deposited near the margin of a Late-glacial ice-dammed lake near Achnasheen, northern Scotland, are described and interpreted. The subglacial sediments consist of deformation tills and glacitectonites derived from pre-existing glaciolacustrine deposits, and the subaqueous sediments consist of ice-proximal outwash and sediment flow deposits, and distal turbidites. Sediment was delivered from the glacier to the lake by two main processes: (1) subglacial till deformation, which fed debris flows at the grounding line; and (2) meltwater transport, which fed sediment-gravity flows on prograding outwash fans. Beyond the ice-marginal environment, deposition was from turbidity currents, ice-rafting and settling of suspended sediments. The exposures support the conclusion that the presence of a subglacial deforming layer can exert an important influence on sedimentation at the grounding lines of calving glaciers.  相似文献   
65.
It has been shown that at certain frequencies the acoustic backscatter from elastic targets exhibits certain resonance behavior which closely relates to the physical properties of the target such as dimension, thickness, and composition. The purpose of this paper is to develop an automated approach for identifying the presence of resonance in the acoustic backscatter from an unknown underwater target by isolating the resonance part from the specular contribution. An adaptive transversal filter structure is used to estimate the specular part of the backscatter and consequently the error signal would provide an estimate of the resonance part. An important aspect of this scheme lies in the fact that it does not require an underlying model for the elastic return. The adaptation rule is based upon fast recursive least squares (RLS) learning. The approach taken in this paper is general in the sense that it can be applied to targets of unknown geometry and thickness and, further, does not require any a priori information about the target and/or the environment. Test results on acoustic data are presented which indicate the effectiveness of the proposed approach  相似文献   
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Book reviews     
Howard  R. F.  van den Oord  G. H. J.  Švestka  Z. 《Solar physics》1996,169(1):225-227
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We examine a siphon-like mechanism for moving mass from the chromosphere to a gravitational well at the top of a magnetic loop to form a prominence. The calculations assume no apriori flow velocity at the loop base. Instead heating in the loop legs drives the flow. The prominence formation process requires two steps. First, the background heating rate must be reduced to on the order of 1 % of the initial heating rate required to maintain the coronal loop. This forms an initial condensation at the top of the loop. Second, the heating must take place only in the loop legs in order to produce a pressure differential which drives mass up into the well at the top of the loop. The heating rate in the loop must be increased once the prominence has begun to form or full prominence densities can not be achieved in a reasonable time. We conclude that this heating driven siphon-like mechanism is feasible for producing and maintaining prominences.  相似文献   
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The supply rates of Na and K to the atmosphere of Mercury by processes acting on the extreme surface—thermal vaporization, photon-stimulated desorption (PSD), and ion-sputtering—are limited by the rates at which atoms can be supplied to the extreme surface by diffusion from inside the regolith grains. Supply rates to the atmosphere are further regulated by ion retention and by gardening rates that supply new grains to the surface. We consider the limits on supply of sodium and potassium atoms to the atmosphere, and rates of photoion recycling to the surface. Thermal vaporization rates are severely limited by the ability of atoms to diffuse to the surface of the grain. Therefore, the diffusion-limited thermal vaporization rates on Mercury's surface are comparable to or less than the PSD rates. Ion sputtering is primarily due to highly ionized heavy ions, even though they represent a small fraction of the solar wind. We have shown that up to 60% of the Na photoions are deposited on the surface of Mercury. Ion recycling to the surface can have a long-term effect on the regolith abundance if an average recycling pattern persists such that more ions return to a particular area than are launched there. It is unknown whether the formation of latitude bands of >100% ion retention persist on average despite a rapidly changing magnetosphere. The total exospheric column of sodium observed at Mercury between 1997 to 2003 varied by a factor of 2-3 from perihelion to aphelion.  相似文献   
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